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First- and Second-Generation Biodiesel & Bionaphtha: Understanding the Differences and Opportunities

As the global energy and chemical sectors pivot toward decarbonization, renewable fuels such as biodiesel and bionaphtha are gaining momentum. But not all renewable fuels are created equal. Here’s a breakdown of first-generation and second-generation biodiesel, as well as bionaphtha, highlighting how they are produced and where they are used.

1st Generation Biodiesel (FAME)

  • Process & Feedstocks: Produced via transesterification of vegetable oils (rapeseed, soybean, palm) or animal fats with methanol. This yields fatty acid methyl esters (FAME) — the main form of biodiesel used in Europe under EN 14214.
  • Applications: Blended with diesel fuel for road transport. Typical blend levels range from B5 to B20, while B100 is used in specially adapted engines.
  • Limitations: Competes with food crops for arable land and has limited cold flow and oxidation stability.

2nd Generation Biodiesel (HVO / Renewable Diesel)

  • Process & Feedstocks: Produced through hydroprocessing (hydrotreatment) of waste oils, used cooking oil (UCO), animal fats, and other advanced waste biomass. The process removes oxygen and saturates the molecules, resulting in a high-quality hydrotreated vegetable oil (HVO) or renewable diesel.
  • Applications: Drop-in fuel with properties similar or superior to fossil diesel. Compatible with existing diesel engines and infrastructure without blending limits.
  • Advantages: Higher cetane number, better cold performance, no FAME-related engine issues, and uses non-food waste streams.

Bionaphtha

  • Process & Feedstocks: A by-product of HVO or bioethanol production, bionaphtha is derived from the same waste and residue feedstocks used for HVO (e.g. UCO, tallow, tall oil).
  • Applications:
    • Fuel sector: Used as a blending component in gasoline.
    • Petrochemicals: Serves as a renewable feedstock for cracking into ethylene and propylene — the basis for plastics, detergents, and synthetic materials.
  • Market Outlook: With growing demand for sustainable petrochemical inputs, bionaphtha plays a key role in defossilizing the plastics value chain.
    More details on this evolving market can be found in S&P Global’s bionaphtha overview.

As clean energy transitions accelerate, the shift from food-based to waste-based biodiesel — and the emergence of biobased petrochemical inputs like bionaphtha — will be essential to meeting sustainability goals.

If you’re sourcing feedstocks for biodiesel or renewable naphtha, contact Prime Elements — your partner in reliable, traceable, and sustainable raw materials.